廖良生教授课题组
FUNSOM
导师语录


1.现代社会竞争激烈,因此,每个学生一定要提高自我核心竞争力;



2.每个学生要努力践行

“养天地正气,法古今完人“的苏大校训,力求将自己培养成德才兼备的现代青年;



3.我们要努力创造OLED技术的自主知识产权,在我国形成“养土鸡--喂土饲料--生土鸡蛋”的全自主产业链发展模式;



4.学术报告中所使用的PPT演示文稿,是报告人的学术面容。我们一定要认真学会如何作学术报告、如何准备高质量的演示文稿,为今后的事业发展,不断提高学术交流能力;




5.想问题时,要异想天开;做事情时,要脚踏实地。





6. CH Lin, YC Chiu, Y Chi, YT Tao, LS Liao, MR Tseng, GH Lee Organometallics 31 (2012), 4349.
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Mechanistic Investigation of Improved Syntheses of Iridium (III)-Based OLED Phosphors


      Treatment of [IrCl3 (tht) 3](tht= tetrahydrothiophene) with a stoichiometric amount of PPh3 gave the monosubstitution product [Ir (tht) 2 (PPh3) Cl3](5), whose synthesis, particularly that leading to the effective preparation of OLED phosphors, was studied and optimized to achieve the best product yields. Thus, the independent treatment of 5 with 2, 4-difluorophenylpyridine (dfppyH) or with variable amounts of benzyldiphenylphosphine (bdpH) gave rise to the formation of the cyclometalation products [Ir (dfppy)(tht)(PPh3) Cl2].